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Highly Anisotropic Glassy Polystyrenes Are Flexible
Author(s) -
Qian Huang,
Jeppe Madsen,
Liyun Yu,
Anine L. Borger,
Sabrina R. Johannsen,
Kell Mortensen,
Ole Hassager
Publication year - 2018
Publication title -
acs macro letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.966
H-Index - 92
ISSN - 2161-1653
DOI - 10.1021/acsmacrolett.8b00485
Subject(s) - materials science , polystyrene , glass transition , composite material , ultimate tensile strength , anisotropy , polymer , quenching (fluorescence) , physics , quantum mechanics , fluorescence
We show that stretching polystyrene melts at a rate faster than the inverse Rouse time, followed by rapid quenching below the glass transition temperature, results in a material that is flexible and remains so for at least six months. Oriented micro/nanofibers are observed in the flexible samples after the mechanical tests. The fibers are probably related to the highly aligned molecules in melt stretching. At room temperature, a tensile strength over 300 MPa has been achieved for the flexible polystyrenes.

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