Synthesis of Elastomeric Liquid Crystalline Polymer Networks via Chain Transfer

Materials capable of complex shape changes have broad reaching applications spanning biomimetic devices, componentless actuators, artificial muscles, and haptic displays. Liquid crystal elastomers (LCE) are a class of shape programmable materials which display anisotropic mechanical deformations in response external stimuli. This work details a synthetic strategy to quickly and efficiently prepare LCEs through the usage of chain transfer agents (CTA). The polyacrylate materials described herein exhibit large, reversible shape changes with strains greater 475%, rivalling properties observed in polysiloxane-based networks. The approach reported here is distinguished in that the materials chemistry is readily amenable to surface alignment techniques. The facile nature of the materials chemistry and the compatibility of these materials with directed self-assembly methods could further enable paradigm shifting end uses as designer substrates for flexible electronics or as actuating surfaces.