Tapered Bottlebrush Polymers: Cone-Shaped Nanostructures by Sequential Addition of Macromonomers | Zendy

Scott C. Radzinski | Zendy; Jeffrey C. Foster | Zendy; Samantha J. Scannelli | Zendy; Jeffrey R. Weaver | Zendy; Kyle J. Arrington | Zendy; John B. Matson | Zendy

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Tapered Bottlebrush Polymers: Cone-Shaped Nanostructures by Sequential Addition of Macromonomers

Author(s) -

Scott C. Radzinski,

Jeffrey C. Foster,

Samantha J. Scannelli,

Jeffrey R. Weaver,

Kyle J. Arrington,

John B. Matson

Publication year - 2017

Publication title -

acs macro letters

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.966

H-Index - 92

ISSN - 2161-1653

DOI - 10.1021/acsmacrolett.7b00724

Subject(s) - romp , materials science , polymer , polystyrene , polymerization , macromonomer , metathesis , polymer chemistry , polymer science , composite material

Tapered (cone-shaped) bottlebrush polymers were synthesized for the first time by ring-opening metathesis polymerization (ROMP) using a sequential-addition of macromonomers (SAM) strategy. Polystyrene macromonomers with molecular weights that increased from 1 to 10 kg mol -1 were polymerized in sequence to high conversion, yielding tapered bottlebrush polymers that could be visualized by atomic force microscopy (AFM).

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