Open AccessIn Situ Nanoscale Investigation of Step Retreat on Fluoranthene Crystal Surfaces
Author(s) -
ClaudiaCorina Giese,
Helen E. King,
Martijn van den Ende,
Oliver Plümper,
I. L. ten Kate,
A. G. G. M. Tielens
Publication year - 2018
Publication title -
acs earth and space chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.876
H-Index - 19
ISSN - 2472-3452
DOI - 10.1021/acsearthspacechem.8b00120
Subject(s) - fluoranthene , dissolution , aqueous solution , solubility , ionic strength , sublimation (psychology) , chemistry , chemical engineering , materials science , environmental chemistry , mineralogy , inorganic chemistry , organic chemistry , phenanthrene , psychology , engineering , psychotherapist
Fluoranthene, a polycyclic aromatic hydrocarbon, has been detected on Earth as well as in asteroids and meteorites and may have played a role in the formation of life. Increasing the ionic strength of aqueous solutions has been observed to lower the fluoranthene solubility, but it is unclear how solution composition controls the release rate of fluoranthene to an aqueous solution. To elucidate this, we performed in situ atomic force microscopy experiments in which we characterized the sublimation and dissolution behavior of fluoranthene crystal surfaces. From this, we quantify the step retreat rate upon exposure to air, deionized water, and a 0.4 M NaCl or 0.1 M MgSO 4 solution. Surface roughness is the main factor that determines the dissolution or sublimation rate. The results imply that during fluoranthene remediation or breakdown in meteorites and asteroids, ionic strength will be more important than chemical composition for controlling fluoranthene release into solution.
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