Interfacial Control of Catalytic Activity in the Aldol Condensation: Combining the Effects of Hydrophobic Environments and Water | Zendy

Dilini SingappuliArachchige | Zendy; Takeshi Kobayashi | Zendy; Zhuoran Wang | Zendy; Sadie J. Burkhow | Zendy; Emily A. Smith | Zendy; Marek Pruski | Zendy; Igor I. Slowing | Zendy

Open Access

Interfacial Control of Catalytic Activity in the Aldol Condensation: Combining the Effects of Hydrophobic Environments and Water

Author(s) -

Dilini SingappuliArachchige,

Takeshi Kobayashi,

Zhuoran Wang,

Sadie J. Burkhow,

Emily A. Smith,

Marek Pruski,

Igor I. Slowing

Publication year - 2019

Publication title -

acs catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 4.898

H-Index - 198

ISSN - 2155-5435

DOI - 10.1021/acscatal.9b00195

Subject(s) - chemistry , catalysis , silanol , amine gas treating , mesoporous silica , active site , mesoporous material , aqueous solution , aldol reaction , chemical engineering , photochemistry , inorganic chemistry , combinatorial chemistry , organic chemistry , engineering

Aminopropyl-functionalized mesoporous silica nanoparticles (AP-MSN) catalyze aldol condensations. The activity of AP-MSN decreases with increasing solvent polarity due to the stabilization of ion p...

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