Expanding the Spectrum of Light-Driven Peroxygenase Reactions | Zendy

Sébastien J.P. Willot | Zendy; Elena FernándezFueyo | Zendy; Florian Tieves | Zendy; Milja Pesic | Zendy; Miguel Alcalde | Zendy; Isabel W. C. E. Arends | Zendy; Chan Beum Park | Zendy; Frank Hollmann | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Open Access

Expanding the Spectrum of Light-Driven Peroxygenase Reactions

Author(s) -

Sébastien J.P. Willot,

Elena FernándezFueyo,

Florian Tieves,

Milja Pesic,

Miguel Alcalde,

Isabel W. C. E. Arends,

Chan Beum Park,

Frank Hollmann

Publication year - 2018

Publication title -

acs catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 4.898

H-Index - 198

ISSN - 2155-5435

DOI - 10.1021/acscatal.8b03752

Subject(s) - formate , photocatalysis , visible spectrum , photochemistry , catalysis , chemistry , scope (computer science) , nanotechnology , combinatorial chemistry , hydrogen peroxide , materials science , computer science , optoelectronics , organic chemistry , programming language

Peroxygenases require a controlled supply of H 2 O 2 to operate efficiently. Here, we propose a photocatalytic system for the reductive activation of ambient O 2 to produce H 2 O 2 which uses the energy provided by visible light more efficiently based on the combination of wavelength-complementary photosensitizers. This approach was coupled to an enzymatic system to make formate available as a sacrificial electron donor. The scope and current limitations of this approach are reported and discussed.

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research