Some Singular Features of Gold Catalysis: Protection of Gold(I) Catalysts by Substoichiometric Agents and Associated Phenomena | Zendy

Camino Bartolomé | Zendy; Zoraida Ramiro | Zendy; Marconi N. PeñasDefrutos | Zendy; Pablo Espinet | Zendy

Open Access

Some Singular Features of Gold Catalysis: Protection of Gold(I) Catalysts by Substoichiometric Agents and Associated Phenomena

Author(s) -

Camino Bartolomé,

Zoraida Ramiro,

Marconi N. PeñasDefrutos,

Pablo Espinet

Publication year - 2016

Publication title -

acs catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 4.898

H-Index - 198

ISSN - 2155-5435

DOI - 10.1021/acscatal.6b01825

Subject(s) - disproportionation , catalysis , chemistry , decomposition , ligand (biochemistry) , ion , solvent , medicinal chemistry , photochemistry , combinatorial chemistry , organic chemistry , receptor , biochemistry

Producción CientíficaThe reaction of [Au(C≡CnBu)]n with [Pd(η3-allyl)Cl(PPh3)] results in a ligand and alkynyl rearrangement, and leads to the heterometallic complex [Pd(η3-allyl){Au(C≡CnBu)2}]2 (3) with an unprecedented bridging bisalkynyl gold ligand coordinated to palladium. This is a formal gold to gold transmetalation that occurs through reversible alkynyl transmetalations between gold and palladium.Ministerio de Economía, Industria y Competitividad (CTQ2013-48406-P)Junta de Castilla y León (programa de apoyo a proyectos de investigación – Ref. VA064U13

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