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Producción CientíficaThe reaction of [Au(C≡CnBu)]n with [Pd(η3-allyl)Cl(PPh3)]results in a ligand and alkynyl rearrangement, and leads to the heterometallic complex [Pd(η3-allyl){Au(C≡CnBu)2}]2 (3) with an unprecedented bridging bisalkynyl gold ligand coordinated to palladium. This is a formal gold to gold transmetalation that occurs through reversible alkynyl transmetalations between gold and palladium.Ministerio de Economía, Industria y Competitividad (CTQ2013-48406-P)Junta de Castilla y León (programa de apoyo a proyectos de investigación – Ref. VA064U13

Some Singular Features of Gold Catalysis: Protection of Gold(I) Catalysts by Substoichiometric Agents and Associated Phenomena