Moisture-Tolerant Frustrated Lewis Pair Catalyst for Hydrogenation of Aldehydes and Ketones | Zendy

Ádám Gyömöre | Zendy; Mária Bakos | Zendy; Tamás Földes | Zendy; Imre Pápai | Zendy; Attila Domján | Zendy; Tibor Soós | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Open Access

Moisture-Tolerant Frustrated Lewis Pair Catalyst for Hydrogenation of Aldehydes and Ketones

Author(s) -

Ádám Gyömöre,

Mária Bakos,

Tamás Földes,

Imre Pápai,

Attila Domján,

Tibor Soós

Publication year - 2015

Publication title -

acs catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 4.898

H-Index - 198

ISSN - 2155-5435

DOI - 10.1021/acscatal.5b01299

Subject(s) - frustrated lewis pair , catalysis , lewis acids and bases , borane , chemistry , organic chemistry

In this paper, we report on the development of a bench-stable borane for frustrated Lewis pair catalyzed reduction of aldehydes, ketones, and enones. The deliberate fine-tuning of structural and electronic parameters of Lewis acid component and the choice of Lewis base provided for the first time, a moisture-tolerant FLP catalyst. Related NMR and DFT studies underpinned the unique behavior of this FLP catalyst and gave insight into the catalytic activity of the resulting FLP catalyst.

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research