Bimetallic Zn and Hf on Silica Catalysts for the Conversion of Ethanol to 1,3-Butadiene | Zendy

Trees De Baerdemaeker | Zendy; Mathias Feyen | Zendy; Ulrich Müller | Zendy; Bilge Yilmaz | Zendy; FengShou Xiao | Zendy; Weiping Zhang | Zendy; Toshiyuki Yokoi | Zendy; Xinhe Bao | Zendy; Hermann Gies | Zendy; Dirk De Vos | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Open Access

Bimetallic Zn and Hf on Silica Catalysts for the Conversion of Ethanol to 1,3-Butadiene

Author(s) -

Trees De Baerdemaeker,

Mathias Feyen,

Ulrich Müller,

Bilge Yilmaz,

FengShou Xiao,

Weiping Zhang,

Toshiyuki Yokoi,

Xinhe Bao,

Hermann Gies,

Dirk De Vos

Publication year - 2015

Publication title -

acs catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 4.898

H-Index - 198

ISSN - 2155-5435

DOI - 10.1021/acscatal.5b00376

Subject(s) - catalysis , bimetallic strip , 1,3 butadiene , dehydration , ethanol , chemistry , inorganic chemistry , nuclear chemistry , organic chemistry , biochemistry

Silica-supported catalysts for the conversion of ethanol to 1,3-butadiene were investigated. The combination of Hf(IV) and Zn(II) resulted in a stable, active, and selective catalyst in which the Zn(II) effectively suppressed the dehydration activity of Hf(IV); the catalyst preparation method plays a crucial role. Using the crystalline Zn-silicate hemimorphite as an alternative Zn(II) source proved to be even more successful in suppressing ethanol dehydration.

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research