Enhanced Photocatalytic and Antibacterial Ability of Cu-Doped Anatase TiO2 Thin Films: Theory and Experiment
Author(s) -
Abdullah M. Alotaibi,
Benjamin A. D. Williamson,
Sanjayan Sathasivam,
Andreas Kafizas,
Mahdi Alqahtani,
Carlos Sotelo-Vázquez,
John Buckeridge,
Jiang Wu,
Sean P. Nair,
David O. Scanlon,
Ivan P. Parkin
Publication year - 2020
Publication title -
acs applied materials and interfaces
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.535
H-Index - 228
eISSN - 1944-8252
pISSN - 1944-8244
DOI - 10.1021/acsami.9b22056
Subject(s) - anatase , materials science , photocatalysis , photoluminescence , thin film , doping , density functional theory , chemical engineering , nanotechnology , chemical vapor deposition , absorption spectroscopy , optoelectronics , optics , organic chemistry , computational chemistry , catalysis , chemistry , engineering , physics
Multifunctional thin films which can display both photocatalytic and antibacterial activity are of great interest industrially. Here, for the first time, we have used aerosol-assisted chemical vapor deposition to deposit highly photoactive thin films of Cu-doped anatase TiO 2 on glass substrates. The films displayed much enhanced photocatalytic activity relative to pure anatase and showed excellent antibacterial (vs Staphylococcus aureus and Escherichia coli ) ability. Using a combination of transient absorption spectroscopy, photoluminescence measurements, and hybrid density functional theory calculations, we have gained nanoscopic insights into the improved properties of the Cu-doped TiO 2 films. Our analysis has highlighted that the interactions between substitutional and interstitial Cu in the anatase lattice can explain the extended exciton lifetimes observed in the doped samples and the enhanced UV photoactivities observed.
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