Synthesis of a Porous C3N-Derived Framework with High Yield by Gallic Acid Cross-Linking Using Salt Melts
Author(s) -
Zhihong Tian,
Tobias Heil,
Johannes Schmidt,
Shaokui Cao,
Markus Antonietti
Publication year - 2020
Publication title -
acs applied materials and interfaces
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.535
H-Index - 228
eISSN - 1944-8252
pISSN - 1944-8244
DOI - 10.1021/acsami.9b20478
Subject(s) - materials science , porosity , salt (chemistry) , yield (engineering) , chemical engineering , molecule , small molecule , condensation , nanotechnology , gallic acid , porous medium , carbon fibers , organic chemistry , composite material , composite number , thermodynamics , chemistry , engineering , antioxidant , physics , biology , genetics
Porous carbon/nitrogen frameworks are an emerging class of noble organic materials with a wide range of potential applications. However, the design and controlled synthesis of those materials are still a challenge. Herein, we present the rational design of such a system with high microporosity, specific surface areas of up to 946 m 2 g -1 , and excellent condensation yields. The obtained noble frameworks were used for the delivery of larger organic molecules and changed the melting behavior of some daily drug molecules along their highly polarizable surfaces.
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