Control of Polar Orientation and Lattice Strain in Epitaxial BaTiO3 Films on Silicon
Author(s) -
Jike Lyu,
Saúl Estandía,
Jaume Gázquez,
Matthew F. Chisholm,
Ignasi Fina,
N. Dix,
J. Fontcuberta,
F. Sánchez
Publication year - 2018
Publication title -
acs applied materials and interfaces
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.535
H-Index - 228
eISSN - 1944-8252
pISSN - 1944-8244
DOI - 10.1021/acsami.8b07778
Subject(s) - materials science , epitaxy , ferroelectricity , wafer , pulsed laser deposition , strain engineering , silicon , perpendicular , thin film , optoelectronics , lattice (music) , substrate (aquarium) , polar , lattice constant , condensed matter physics , composite material , nanotechnology , diffraction , optics , dielectric , layer (electronics) , geology , acoustics , astronomy , oceanography , geometry , mathematics , physics
Conventional strain engineering of epitaxial ferroelectric oxide thin films is based on the selection of substrates with a suitable lattice parameter. Here, we show that the variation of oxygen pressure during pulsed laser deposition is a flexible strain engineering method for epitaxial ferroelectric BaTiO 3 films either on perovskite substrates or on Si(001) wafers. This unconventional growth strategy permits continuous tuning of strain up to high levels (ε > 0.8%) in films greater than one hundred nanometers thick, as well as selecting the polar axis orientation to be either parallel or perpendicular to the substrate surface plane.
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