Substrate-Independent Epitaxial Growth of the Metal–Organic Framework MOF-508a | Zendy

Mark R. Wilson | Zendy; S.N. Barrientos-Palomo | Zendy; Phil Stevens | Zendy; N. L. Mitchell | Zendy; Gerda Oswald | Zendy; C. M. Nagaraja | Zendy; J. P. S. Badyal | Zendy

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Substrate-Independent Epitaxial Growth of the Metal–Organic Framework MOF-508a

Author(s) -

Mark R. Wilson,

S.N. Barrientos-Palomo,

Phil Stevens,

N. L. Mitchell,

Gerda Oswald,

C. M. Nagaraja,

J. P. S. Badyal

Publication year - 2018

Publication title -

acs applied materials and interfaces

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 2.535

H-Index - 228

eISSN - 1944-8252

pISSN - 1944-8244

DOI - 10.1021/acsami.7b16029

Subject(s) - materials science , epitaxy , microporous material , metal organic framework , chemical engineering , imidazole , substrate (aquarium) , layer (electronics) , benzene , crystal growth , surface modification , metal , nanotechnology , crystallography , organic chemistry , adsorption , composite material , metallurgy , chemistry , oceanography , geology , engineering

Plasmachemical deposition is a substrate-independent method for the conformal surface functionalization of solid substrates. Structurally well-defined pulsed plasma deposited poly(1-allylimidazole) layers provide surface imidazole linker groups for the directed liquid-phase epitaxial (layer-by-layer) growth of metal-organic frameworks (MOFs) at room temperature. For the case of microporous [Zn (benzene-1,4-dicarboxylate)-(4,4'-bipyridine) 0.5 ] (MOF-508), the MOF-508a polymorph containing two interpenetrating crystal lattice frameworks undergoes orientated Volmer-Weber growth and displays CO 2 gas capture behavior at atmospheric concentrations in proportion to the number of epitaxially grown MOF-508 layers.

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