Facile Method for the Preparation of Covalent Triazine Framework coated Monoliths as Catalyst Support: Applications in C1 Catalysis | Zendy

Anastasiya Bavykina | Zendy; Alma I. Olivos Suarez | Zendy; Dmitrii Osadchii | Zendy; Rahul Valecha | Zendy; Robert Franz | Zendy; Michiel Makkee | Zendy; Freek Kapteijn | Zendy; Jorge Gascón | Zendy

Open Access

Facile Method for the Preparation of Covalent Triazine Framework coated Monoliths as Catalyst Support: Applications in C1 Catalysis

Author(s) -

Anastasiya Bavykina,

Alma I. Olivos Suarez,

Dmitrii Osadchii,

Rahul Valecha,

Robert Franz,

Michiel Makkee,

Freek Kapteijn,

Jorge Gascón

Publication year - 2017

Publication title -

acs applied materials and interfaces

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 2.535

H-Index - 228

eISSN - 1944-8252

pISSN - 1944-8244

DOI - 10.1021/acsami.7b07339

Subject(s) - catalysis , materials science , triazine , cordierite , microreactor , chemical engineering , catalyst support , formic acid , covalent bond , monolith , heterogeneous catalysis , polymer , porosity , slurry , organic chemistry , polymer chemistry , chemistry , composite material , engineering

A quasi chemical vapor deposition method for the manufacture of well-defined covalent triazine framework (CTF) coatings on cordierite monoliths is reported. The resulting supported porous organic polymer is an excellent support for the immobilization of two different homogeneous catalysts: (1) an Ir III Cp*-based catalyst for the hydrogen production from formic acid and (2) a P II -based catalyst for the direct activation of methane via Periana chemistry. The immobilized catalysts display a much higher activity in comparison with the unsupported CTF operated in slurry because of improved mass transport. Our results demonstrate that CTF-based catalysts can be further optimized by engineering at different length scales.

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