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Brine-Soluble Zwitterionic Copolymers with Tunable Adsorption on Rocks
Author(s) -
Yuan He,
Haleema Alamri,
Mohammed Kawelah,
Ayrat Gizzatov,
Mariam F. Alghamdi,
Timothy M. Swager,
Shahong Zhu
Publication year - 2020
Publication title -
acs applied materials and interfaces
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.535
H-Index - 228
eISSN - 1944-8252
pISSN - 1944-8244
DOI - 10.1021/acsami.0c02247
Subject(s) - adsorption , copolymer , polymer , brine , materials science , chemical engineering , enhanced oil recovery , aqueous solution , monomer , petroleum , organic chemistry , composite material , chemistry , engineering
Injection of aqueous fluids into reservoirs as an enhanced oil recovery (EOR) tool has been of great interest in petroleum engineering. EOR using viscous polymer solutions improves the volumetric sweep efficiency. However, significant polymer adsorption on reservoir rock surfaces is one of the greatest challenges in polymer-flooding EOR. We have synthesized and characterized five zwitterionic copolymers and studied their static adsorption on limestone surfaces in seawater at high temperatures and salinities. Our results indicate that polymer adsorption directly correlates to a small percentage of functional co-monomers on the polymer backbone. One particular copolymer shows negligible static adsorption on limestone surfaces.

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