Green-Light Activatable, Water-Soluble Red-Shifted Coumarin Photocages
Author(s) -
Márton Bojtár,
Attila Kormos,
Katalin KisPetik,
Miklós Kellermayer,
Péter Kele
Publication year - 2019
Publication title -
organic letters
Language(s) - Uncategorized
Resource type - Journals
SCImago Journal Rank - 1.94
H-Index - 239
eISSN - 1523-7060
pISSN - 1523-7052
DOI - 10.1021/acs.orglett.9b03624
Subject(s) - chemistry , coumarin , bodipy , water soluble , aqueous solution , solubility , absorption (acoustics) , photochemistry , red light , fluorescence , organic chemistry , optics , botany , biology , physics
Easily accessible green-light activatable (>500 nm) photocages based on red-shifted, π-extended coumarin scaffolds are developed with uncaging efficiencies similar to those of recently introduced BODIPY derivatives. The photocages possess increased aqueous solubility, high absorption coefficients within the 450-600 nm range, and exceptionally high two-photon cross sections.
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