Open AccessNickel-Catalyzed Synthesis of Silanes from Silyl Ketones
Author(s) -
Watchara Srimontree,
Waranya Lakornwong,
Magnus Rueping
Publication year - 2019
Publication title -
organic letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.94
H-Index - 239
eISSN - 1523-7060
pISSN - 1523-7052
DOI - 10.1021/acs.orglett.9b03487
Subject(s) - silylation , silanes , chemistry , catalysis , intramolecular force , nickel , organic chemistry , combinatorial chemistry , silane
An unprecedented nickel-catalyzed decarbonylative silylation via CO extrusion intramolecular recombination fragment coupling of unstrained and nondirecting group-assisted silyl ketones is described. The inexpensive and readily available catalyst performs under mild reaction conditions and enables the synthesis of structurally diverse arylsilanes, including heterocyclic and natural product derivatives.
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