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Bis(dimethylamino)phosphorodiamidate (BDMDAP) enables an efficient and one-pot cyclophosphorylation of vicinal cis -diol moiety of polyol-organics of biological importance without the need for protecting group chemistry and is amenable to large-scale reactions. The utility of this reagent is demonstrated through the synthesis of high-value targets such as cyclic phosphates of myo -inositol, nucleosides, metabolites, and drug molecules.

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Bis(dimethylamino)phosphorodiamidate: A Reagent for the Regioselective Cyclophosphorylation of<i>cis</i>-Diols Enabling One-Step Access to High-Value Target Cyclophosphates

Bis(dimethylamino)phosphorodiamidate: A Reagent for the Regioselective Cyclophosphorylation ofcis-Diols Enabling One-Step Access to High-Value Target Cyclophosphates