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A silver-tetrafluoroborate- or HBF 4 -catalyzed ortho- alkylation reaction of phenols and diarylamines with styrenes has been explored. A broad substrate scope is presented as well as mechanistic experiments and discussion.

HBF4- and AgBF4-Catalyzed ortho-Alkylation of Diarylamines and Phenols

HBF₄- and AgBF₄-Catalyzed ortho-Alkylation of Diarylamines and Phenols