Open AccessHBF4- and AgBF4-Catalyzed ortho-Alkylation of Diarylamines and Phenols
Author(s) -
Christian Rank,
Bünyamin Özkaya,
Frédéric W. Patureau
Publication year - 2019
Publication title -
organic letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.94
H-Index - 239
eISSN - 1523-7060
pISSN - 1523-7052
DOI - 10.1021/acs.orglett.9b02470
Subject(s) - chemistry , alkylation , phenols , catalysis , tetrafluoroborate , scope (computer science) , substrate (aquarium) , organic chemistry , medicinal chemistry , ionic liquid , oceanography , computer science , programming language , geology
A silver-tetrafluoroborate- or HBF 4 -catalyzed ortho- alkylation reaction of phenols and diarylamines with styrenes has been explored. A broad substrate scope is presented as well as mechanistic experiments and discussion.
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