Semiheterogeneous Dual Nickel/Photocatalytic (Thio)etherification Using Carbon Nitrides | Zendy

Cristian Cavedon | Zendy; Amiera Madani | Zendy; Peter H. Seeberger | Zendy; Bartholomäus Pieber | Zendy

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Semiheterogeneous Dual Nickel/Photocatalytic (Thio)etherification Using Carbon Nitrides

Author(s) -

Cristian Cavedon,

Amiera Madani,

Peter H. Seeberger,

Bartholomäus Pieber

Publication year - 2019

Publication title -

organic letters

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.94

H-Index - 239

eISSN - 1523-7060

pISSN - 1523-7052

DOI - 10.1021/acs.orglett.9b01957

Subject(s) - aryl , chemistry , catalysis , intramolecular force , photocatalysis , thio , nickel , carbon nitride , carbon fibers , nitride , metal , combinatorial chemistry , organic chemistry , materials science , alkyl , layer (electronics) , composite number , composite material

A carbon nitride material can be combined with homogeneous nickel catalysts for light-mediated cross-couplings of aryl bromides with alcohols under mild conditions. The metal-free heterogeneous semiconductor is fully recyclable and couples a broad range of electron-poor aryl bromides with primary and secondary alcohols as well as water. The application for intramolecular reactions and the synthesis of active pharmaceutical ingredients was demonstrated. The catalytic protocol is applicable for the coupling of aryl iodides with thiols as well.

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