Oxidative Cross-Coupling of Boron and Antimony Nucleophiles via Palladium(I) | Zendy

Quillon J. Simpson | Zendy; Matthew J. G. Sinclair | Zendy; David W. Lupton | Zendy; Adrian B. Chaplin | Zendy; Joel F. Hooper | Zendy

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Oxidative Cross-Coupling of Boron and Antimony Nucleophiles via Palladium(I)

Author(s) -

Quillon J. Simpson,

Matthew J. G. Sinclair,

David W. Lupton,

Adrian B. Chaplin,

Joel F. Hooper

Publication year - 2018

Publication title -

organic letters

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.94

H-Index - 239

eISSN - 1523-7060

pISSN - 1523-7052

DOI - 10.1021/acs.orglett.8b01989

Subject(s) - nucleophile , chemistry , antimony , aryl , palladium , selectivity , boron , catalysis , oxidative phosphorylation , monomer , combinatorial chemistry , coupling (piping) , organic chemistry , mechanical engineering , biochemistry , alkyl , polymer , engineering

The use of an isolatable, monomeric Pd(I) complex as a catalyst for the oxidative cross-coupling of aryl-antimony and aryl-boron nucleophiles is reported. This reaction tolerates a wide variety of substrates, with >20:1 selectivity for cross-coupled products. This strategy offers a new approach to achieving the selective cross-coupling of nucleophiles.

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