Sulfonimidates: Useful Synthetic Intermediates for Sulfoximine Synthesis via C–S Bond Formation | Zendy

Priscilla Mendonça Matos | Zendy; William Lewis | Zendy; Jonathan C. Moore | Zendy; Robert A. Stockman | Zendy

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Sulfonimidates: Useful Synthetic Intermediates for Sulfoximine Synthesis via C–S Bond Formation

Author(s) -

Priscilla Mendonça Matos,

William Lewis,

Jonathan C. Moore,

Robert A. Stockman

Publication year - 2018

Publication title -

organic letters

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.94

H-Index - 239

eISSN - 1523-7060

pISSN - 1523-7052

DOI - 10.1021/acs.orglett.8b01473

Subject(s) - chemistry , reagent , combinatorial chemistry , oxidative coupling of methane , coupling (piping) , oxidative phosphorylation , organic chemistry , catalysis , biochemistry , mechanical engineering , engineering

Medicinally relevant sulfoximines are accessed from C-S coupling of sulfonimidates and commercially available organomagnesium reagents. Sulfonimidates are conveniently synthesized by oxidative alkoxylation of readily available sulfinamides. This constitutes a general C-S coupling approach for the synthesis of sulfoximines.

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