Metal Actuated Ring Translocation Switches in Water | Zendy

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Metal Actuated Ring Translocation Switches in Water

Author(s) -

Hang Yin,

Roselyne Rosas,

Didier Gigmès,

Olivier Ouari,

Ruibing Wang,

Anthony Kermagoret,

David Bardelang

Publication year - 2018

Publication title -

organic letters

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.94

H-Index - 239

eISSN - 1523-7060

pISSN - 1523-7052

DOI - 10.1021/acs.orglett.8b01019

Subject(s) - chemistry , chromosomal translocation , ring (chemistry) , metal , nanotechnology , organic chemistry , biochemistry , gene , materials science

Among a series of metal ions in water, silver is the only one to remotely and reversibly switch cucurbit[7]uril (CB[7]) movements (translocation or uptake) on a rigid and linear three-station viologen-phenylene-imidazole ( V-P-I) derivative, avoiding undesired pH actuation. 1 H NMR, UV-vis spectroscopy, mass spectrometry, ITC, and modeling were combined to show that ring translocation or uptake along a molecular thread is possible in water by Ag + as a metal stimulus.

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