Open AccessRhodium(II)-Alkynyl Carbenoids Insertion into Si–H bonds: An Entry to Propargylic Geminal Bis(silanes)
Author(s) -
Thibaut Courant,
Rahul Kumar,
Serge Turcaud,
Laurent Micouin
Publication year - 2016
Publication title -
organic letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.94
H-Index - 239
eISSN - 1523-7060
pISSN - 1523-7052
DOI - 10.1021/acs.orglett.6b02264
Subject(s) - geminal , silanes , rhodium , chemistry , reactivity (psychology) , catalysis , medicinal chemistry , stereochemistry , organic chemistry , silane , medicine , alternative medicine , pathology
α-Alkynyl-α'-trimethylsilylhydrazones are used as novel Rh(II)-carbenoids precursors. These new carbenoids have shown very good reactivity in Si-H insertion reactions, leading to original propargylic geminal-bis(silanes) in a two-step sequential process.
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