Nickel-Catalyzed Decarboxylative Cross-Coupling of Perfluorobenzoates with Aryl Halides and Sulfonates | Zendy

Logan W. Sardzinski | Zendy; William C. Wertjes | Zendy; Abigail Schnaith | Zendy; Dipannita Kalyani | Zendy

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Nickel-Catalyzed Decarboxylative Cross-Coupling of Perfluorobenzoates with Aryl Halides and Sulfonates

Author(s) -

Logan W. Sardzinski,

William C. Wertjes,

Abigail Schnaith,

Dipannita Kalyani

Publication year - 2015

Publication title -

organic letters

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.94

H-Index - 239

eISSN - 1523-7060

pISSN - 1523-7052

DOI - 10.1021/acs.orglett.5b00241

Subject(s) - halide , aryl , chemistry , catalysis , nickel , coupling (piping) , decarboxylation , coupling reaction , combinatorial chemistry , organic chemistry , alkyl , mechanical engineering , engineering

A Ni-catalyzed method for the coupling of perfluorobenzoates with aryl halides and pseudohalides is described. Aryl iodides, bromides, chlorides, triflates, and tosylates participate in these transformations to afford the products in good yields. Penta-, tetra-, and trifluorinated biaryl compounds are obtained using these newly developed Ni-catalyzed decarboxylative cross-coupling reactions.

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