Open AccessPalladium-Catalyzed Sulfinylation of Aryl- and Alkenylborons with Sulfinate Esters
Author(s) -
Minori Suzuki,
Kazuya Kanemoto,
Yu Nakamura,
Takamitsu Hosoya,
Suguru Yoshida
Publication year - 2021
Publication title -
organic letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.94
H-Index - 239
eISSN - 1523-7060
pISSN - 1523-7052
DOI - 10.1021/acs.orglett.1c01292
Subject(s) - organosulfur compounds , palladium , chemistry , aryl , sulfoxide , catalysis , organic chemistry , sulfone , combinatorial chemistry , sulfur , alkyl
An efficient, direct sulfinylation of organoborons catalyzed by palladium is disclosed. Treatment of organoborons and sulfinate esters in the presence of a palladium precatalyst provided a broad range of sulfoxides. Various organosulfur compounds having oxidizable functional groups were successfully prepared through the sulfoxide synthesis.
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