Triple Stack of a Viologen Derivative in a CB[10] Pair | Zendy

Fengbo Liu | Zendy; Shagor Chowdhury | Zendy; Roselyne Rosas | Zendy; Valérie Monnier | Zendy; Laurence Charles | Zendy; Hakim Karoui | Zendy; Didier Gigmès | Zendy; Olivier Ouari | Zendy; Floris Chevallier | Zendy; Christophe Bucher | Zendy; Anthony Kermagoret | Zendy; Simin Liu | Zendy; David Bardelang | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Open Access

Triple Stack of a Viologen Derivative in a CB[10] Pair

Author(s) -

Fengbo Liu,

Shagor Chowdhury,

Roselyne Rosas,

Valérie Monnier,

Laurence Charles,

Hakim Karoui,

Didier Gigmès,

Olivier Ouari,

Floris Chevallier,

Christophe Bucher,

Anthony Kermagoret,

Simin Liu,

David Bardelang

Publication year - 2021

Publication title -

organic letters

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.94

H-Index - 239

eISSN - 1523-7060

pISSN - 1523-7052

DOI - 10.1021/acs.orglett.1c00773

Subject(s) - chemistry , viologen , stack (abstract data type) , derivative (finance) , combinatorial chemistry , triple bond , stereochemistry , photochemistry , organic chemistry , computer science , operating system , business , double bond , finance

A viologen-phenylene-imidazole ( VPI ) conjugate, previously shown to be singly complexed by CB[7] and doubly bound by CB[8], is herein shown to form antiparallel triple stacks in water with cucurbit[10]uril (CB[10]), pairwise complexing the guest trimer. The quinary host:guest 2:3 complex showed features assignable to charge-transfer interactions. Under reductive conditions, CB[10] could solubilize a VPI radical, even though CB[10] and reduced VPI are almost insoluble, thereby illustrating a possible new application for CB[10].

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research