Higher Analogues of Resorcinarenes and Pyrogallolarenes: Bricks for Supramolecular Chemistry | Zendy

Monika Chwastek | Zendy; Agnieszka Szumna | Zendy

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Higher Analogues of Resorcinarenes and Pyrogallolarenes: Bricks for Supramolecular Chemistry

Author(s) -

Monika Chwastek,

Agnieszka Szumna

Publication year - 2020

Publication title -

organic letters

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.94

H-Index - 239

eISSN - 1523-7060

pISSN - 1523-7052

DOI - 10.1021/acs.orglett.0c02357

Subject(s) - chemistry , supramolecular chemistry , pyrogallol , covalent bond , calixarene , polymer chemistry , organic chemistry , stereochemistry , molecule

Easy scalable and eco-friendly syntheses of resorcin[5]arene, pyrogallol[5]arene, (2-nitro)resorcin[5]arene, (2-carboxyl)resorcin[5]arene, and resorcin[7]arene are presented and a wide range of upper-rim modifications is demonstrated. The macrocycles open the door toward expanding the rich covalent and supramolecular chemistry of [4]arenes with analogues having unique 5-fold and 7-fold symmetry.

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