Photoredox Generation of Sulfonyl Radicals and Coupling with Electron Deficient Olefins | Zendy

Yiding Chen | Zendy; Nicole McNamara | Zendy; Oliver May | Zendy; Thanigaimalai Pillaiyar | Zendy; David C. Blakemore | Zendy; Steven V. Ley | Zendy

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Photoredox Generation of Sulfonyl Radicals and Coupling with Electron Deficient Olefins

Author(s) -

Yiding Chen,

Nicole McNamara,

Oliver May,

Thanigaimalai Pillaiyar,

David C. Blakemore,

Steven V. Ley

Publication year - 2020

Publication title -

organic letters

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.94

H-Index - 239

eISSN - 1523-7060

pISSN - 1523-7052

DOI - 10.1021/acs.orglett.0c01730

Subject(s) - sulfonyl , chemistry , sulfone , radical , photoredox catalysis , photochemistry , catalysis , coupling (piping) , electron , combinatorial chemistry , photocatalysis , organic chemistry , mechanical engineering , alkyl , engineering , physics , quantum mechanics

Various sulfone tetrazoles were activated via iridium photoredox catalysis in the presence of DMAP to give dialkyl sulfones. The presumed sulfone radical intermediates were trapped by a range of electron-deficient olefins in generally good to excellent yields.

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