Open AccessHydrogenation of Benzonitrile over Supported Pd Catalysts: Kinetic and Mechanistic Insight
Author(s) -
Mairi I. McAllister,
Cédric Boulho,
Lauren F. Gilpin,
Liam McMillan,
Colin Brennan,
David Len
Publication year - 2019
Publication title -
organic process research and development
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.904
H-Index - 109
eISSN - 1520-586X
pISSN - 1083-6160
DOI - 10.1021/acs.oprd.9b00058
Subject(s) - benzonitrile , hydrogenolysis , catalysis , benzylamine , chemistry , activation energy , hydrogen , adsorption , photochemistry , organic chemistry
The liquid phase hydrogenation of benzonitrile over a 5 wt % Pd/C catalyst using a stirred autoclave is investigated. The reaction conforms to a consecutive reaction sequence: first benzonitrile is...
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