Partial Dislocations in Graphene and Their Atomic Level Migration Dynamics
Author(s) -
Alex W. Robertson,
GunDo Lee,
Kuang He,
Ye Fan,
Christopher S. Allen,
SungWoo Lee,
Heeyeon Kim,
Euijoon Yoon,
Haimei Zheng,
Angus I. Kirkland,
Jamie H. Warner
Publication year - 2015
Publication title -
nano letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 4.853
H-Index - 488
eISSN - 1530-6992
pISSN - 1530-6984
DOI - 10.1021/acs.nanolett.5b02080
Subject(s) - partial dislocations , graphene , materials science , dislocation , condensed matter physics , diamond , transmission electron microscopy , molecular dynamics , annealing (glass) , high resolution transmission electron microscopy , chemical physics , diamond cubic , crystallography , nanotechnology , chemistry , computational chemistry , physics , composite material
We demonstrate the formation of partial dislocations in graphene at elevated temperatures of ≥500 °C with single atom resolution aberration corrected transmission electron microscopy. The partial dislocations spatially redistribute strain in the lattice, providing an energetically more favorable configuration to the perfect dislocation. Low-energy migration paths mediated by partial dislocation formation have been observed, providing insights into the atomistic dynamics of graphene during annealing. These results are important for understanding the high temperature plasticity of graphene and partial dislocation behavior in related crystal systems, such as diamond cubic materials.
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