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Two-Tier Compatibility of Superelastic Bicrystal Micropillar at Grain Boundary
Author(s) -
Mostafa Karami,
Zeyuan Zhu,
Zhuohui Zeng,
Nobumichi Tamura,
Yong Yang,
Xian Chen
Publication year - 2020
Publication title -
nano letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 4.853
H-Index - 488
eISSN - 1530-6992
pISSN - 1530-6984
DOI - 10.1021/acs.nanolett.0c03486
Subject(s) - compatibility (geochemistry) , materials science , grain boundary , slipping , shape memory alloy , composite material , crystallography , condensed matter physics , microstructure , structural engineering , chemistry , physics , engineering
Both crystallographic compatibility and grain engineering are super critical to the functionality of shape memory alloys, especially at micro- and nanoscales. Here, we report a bicrystal CuAl 24 Mn 9 micropillar engraved at a high-angle grain boundary (GB) that exhibits enhanced reversibility under very demanding driving stress (about 600 MPa) over 10 000 transformation cycles despite its lattice parameters are far from satisfying any crystallographic compatibility conditions. We propose a new compatibility criterion regarding the GB for textured shape memory alloys, which suggests that the formation of GB compatible twin laminates in neighboring textured grains activates an interlock mechanism, which prevents dislocations from slipping across GB.

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