Measuring Long-Range 13C–13C Correlations on a Surface under Natural Abundance Using Dynamic Nuclear Polarization-Enhanced Solid-State Nuclear Magnetic Resonance | Zendy

Takeshi Kobayashi | Zendy; Igor I. Slowing | Zendy; Marek Pruski | Zendy

Open Access

Measuring Long-Range ¹³C–¹³C Correlations on a Surface under Natural Abundance Using Dynamic Nuclear Polarization-Enhanced Solid-State Nuclear Magnetic Resonance

Author(s) -

Takeshi Kobayashi,

Igor I. Slowing,

Marek Pruski

Publication year - 2017

Publication title -

the journal of physical chemistry c

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.401

H-Index - 289

eISSN - 1932-7455

pISSN - 1932-7447

DOI - 10.1021/acs.jpcc.7b08841

Subject(s) - homonuclear molecule , natural abundance , solid state nuclear magnetic resonance , isotope , polarization (electrochemistry) , nuclear reaction , solid state , nuclear magnetic resonance , analytical chemistry (journal) , carbon 13 , molecule , chemistry , materials science , atomic physics , nuclear physics , physics , organic chemistry , chromatography

We report that spatial (<1 nm) proximity between different molecules in solid bulk materials and, for the first time, different moieties on the surface of a catalyst, can be established without isotope enrichment by means of homonuclear CHHC solid-state nuclear magnetic resonance experiment. This 13C–13C correlation measurement, which hitherto was not possible for natural-abundance solids, was enabled by the use of dynamic nuclear polarization. Importantly, it allows the study of long-range correlations in a variety of materials with high resolution.

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