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Cubic Li 7 La 3 Zr 2 O 12 (LLZO), stabilized by supervalent cations, is one of the most promising oxide electrolyte to realize inherently safe all-solid-state batteries. It is of great interest to evaluate the strategy of supervalent stabilization in similar compounds and to describe its effect on ionic bulk conductivity σ' bulk . Here, we synthesized solid solutions of Li 7- x  La 3 M 2- x  Ta  x  O 12 with M = Hf, Sn over the full compositional range ( x = 0, 0.25...2). It turned out that Ta contents at x of 0.25 (M = Hf, LLHTO) and 0.5 (M = Sn, LLSTO) are necessary to yield phase pure cubic Li 7- x  La 3 M 2- x  Ta  x  O 12 . The maximum in total conductivity for LLHTO (2 × 10 -4 S cm -1 ) is achieved for x = 1.0; the associated activation energy is 0.46 eV. At x = 0.5 and x = 1.0, we observe two conductivity anomalies that are qualitatively in agreement with the rule of Meyer and Neldel. For LLSTO, at x = 0.75 the conductivity σ' bulk turned out to be 7.94 × 10 -5 S cm -1 (0.46 eV); the almost monotonic decrease of ion bulk conductivity from x = 0.75 to x = 2 in this series is in line with Meyer-Neldel's compensation behavior showing that a decrease in E  a is accompanied by a decrease of the Arrhenius prefactor. Altogether, the system might serve as an attractive alternative to Al-stabilized (or Ga-stabilized) Li 7 La 3 Zr 2 O 12 as LLHTO is also anticipated to be highly stable against Li metal.

journal of physical chemistry. c./journal of physical chemistry. c

Anomalies in Bulk Ion Transport in the Solid Solutions of Li7La3M2O12 (M = Hf, Sn) and Li5La3Ta2O12