Control of Excited-State Proton-Coupled Electron Transfer by Ultrafast Pump-Push-Probe Spectroscopy in Heptazine-Phenol Complexes: Implications for Photochemical Water Oxidation
Author(s) -
Kathryn L. Corp,
E. Rabe,
Xiang Huang,
Johannes Ehrmaier,
Mitchell E. Kaiser,
Andrzej L. Sobolewski,
Wolfgang Domcke,
Cody W. Schlenker
Publication year - 2020
Publication title -
the journal of physical chemistry c
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.401
H-Index - 289
eISSN - 1932-7455
pISSN - 1932-7447
DOI - 10.1021/acs.jpcc.0c00415
Subject(s) - photochemistry , excited state , chemistry , chromophore , spectroscopy , atomic physics , quantum mechanics , physics
We demonstrate chemical tuning and laser-driven control of intermolecular H atom abstraction from protic solvent molecules. Using multipulse ultrafast pump-push-probe transient absorption (TA) spec...
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