English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

Geometric nanoconfinement, in one and two dimensions, has a fundamental influence on the segmental dynamics of polymer glass-formers and can be markedly different from that observed in the bulk state. In this work, with the use of dielectric spectroscopy, we have investigated the glass transition behavior of poly(2-vinylpyridine) (P2VP) confined within alumina nanopores and prepared as a thin film supported on a silicon substrate. P2VP is known to exhibit strong, attractive interactions with confining surfaces due to the ability to form hydrogen bonds. Obtained results show no changes in the temperature evolution of the α-relaxation time in nanopores down to 20 nm size and 24 nm thin film. There is also no evidence of an out-of-equilibrium behavior observed for other glass-forming systems confined at the nanoscale. Nevertheless, in both cases, the confinement effect is seen as a substantial broadening of the α-relaxation time distribution. We discussed the results in terms of the importance of the interfacial energy between the polymer and various substrates, the sensitivity of the glass-transition temperature to density fluctuations, and the density scaling concept.

On the Segmental Dynamics and the Glass Transition Behavior of Poly(2-vinylpyridine) in One- and Two-Dimensional Nanometric Confinement