BCl3-Activated Synthesis of COO-BODIPY Laser Dyes: General Scope and High Yields under Mild Conditions | Zendy

César Ray | Zendy; Christopher Schad | Zendy; Florencio Moreno | Zendy; Beatriz Lora Maroto | Zendy; Jorge Bañuelos | Zendy; Teresa Arbeloa | Zendy; Inmaculada GarcíaMoreno | Zendy; Cassie Villafuerte | Zendy; Gilles Muller | Zendy; Santiago de la Moya Cerero | Zendy

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BCl₃-Activated Synthesis of COO-BODIPY Laser Dyes: General Scope and High Yields under Mild Conditions

Author(s) -

César Ray,

Christopher Schad,

Florencio Moreno,

Beatriz Lora Maroto,

Jorge Bañuelos,

Teresa Arbeloa,

Inmaculada GarcíaMoreno,

Cassie Villafuerte,

Gilles Muller,

Santiago de la Moya Cerero

Publication year - 2020

Publication title -

the journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.2

H-Index - 228

eISSN - 1520-6904

pISSN - 0022-3263

DOI - 10.1021/acs.joc.9b03059

Subject(s) - chemistry , bodipy , boron , combinatorial chemistry , scope (computer science) , boron trichloride , organic chemistry , photochemistry , fluorescence , physics , computer science , programming language , quantum mechanics

A general and straightforward method for the synthesis of COO-BODIPYs from F-BODIPYs and carboxylic acids is established. The method is based on the use of boron trichloride to activate the involved substitution of fluorine, which leads to high yields through rapid reactions under soft conditions. This mild method opens the way to unprecedented laser dyes with outstanding efficiencies and photostabilities, which are difficult to obtain by the current methods.

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