Aerobic and Ligand-Free Manganese-Catalyzed Homocoupling of Arenes or Aryl Halides via in Situ Formation of Aryllithiums | Zendy

Yujia Liu | Zendy; Julien Bergès | Zendy; Yassir Zaid | Zendy; Fouad Ouazzani Chahdi | Zendy; Arie van der Lee | Zendy; Dominique Harakat | Zendy; Eric Clot | Zendy; Florian Jaroschik | Zendy; Marc Taillefer | Zendy

Open Access

Aerobic and Ligand-Free Manganese-Catalyzed Homocoupling of Arenes or Aryl Halides via in Situ Formation of Aryllithiums

Author(s) -

Yujia Liu,

Julien Bergès,

Yassir Zaid,

Fouad Ouazzani Chahdi,

Arie van der Lee,

Dominique Harakat,

Eric Clot,

Florian Jaroschik,

Marc Taillefer

Publication year - 2019

Publication title -

the journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.2

H-Index - 228

eISSN - 1520-6904

pISSN - 0022-3263

DOI - 10.1021/acs.joc.8b02834

Subject(s) - chemistry , manganese , halide , aryl , ligand (biochemistry) , catalysis , in situ , monomer , polymer chemistry , combinatorial chemistry , organic chemistry , biochemistry , alkyl , receptor , polymer

Ligand-free manganese-catalyzed homocoupling of arenes or aryl halides can be carried out under aerobic conditions via the in situ formation of the corresponding aryllithiums. A wide range of biaryls and derivatives has been obtained, and a mechanism involving monomeric manganese-oxo complexes has been proposed on the basis of DFT calculations.

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