Synthesis of O-1–O-6 Substituted Positional Isomers of d-Glucose–Thioether Ligands and Their Ruthenium Polypyridyl Conjugates | Zendy

Lucien N. Lameijer | Zendy; Julien le Roy | Zendy; Stefan van der Vorm | Zendy; Sylvestre Bonnet | Zendy

Open Access

Synthesis of O-1–O-6 Substituted Positional Isomers of d-Glucose–Thioether Ligands and Their Ruthenium Polypyridyl Conjugates

Author(s) -

Lucien N. Lameijer,

Julien le Roy,

Stefan van der Vorm,

Sylvestre Bonnet

Publication year - 2018

Publication title -

the journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.2

H-Index - 228

eISSN - 1520-6904

pISSN - 0022-3263

DOI - 10.1021/acs.joc.8b01342

Subject(s) - thioether , chemistry , ruthenium , conjugate , sulfur , palladium , stereochemistry , structural isomer , transition metal , combinatorial chemistry , medicinal chemistry , catalysis , organic chemistry , mathematical analysis , mathematics

A library of positional isomers of d-glucose ( O-1- O-6) as ligands and their 11 light-active ruthenium conjugates has been synthesized. A protecting group strategy without the necessity of using palladium on carbon for the modification for the 2- O and 4- O position allows for the incorporation of sulfur donor atoms as ligands for transition metal complexes.

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