Trifluoromethyl Vinyl Sulfide: A Building Block for the Synthesis of CF3S-Containing Isoxazolidines | Zendy

Alejandra RiescoDomínguez | Zendy; Jeroen van de Wiel | Zendy; Trevor A. Hamlin | Zendy; Bas van Beek | Zendy; Stephen D. Lindell | Zendy; Daniel BlancoAnia | Zendy; F. Matthias Bickelhaupt | Zendy; Floris P. J. T. Rutjes | Zendy

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Trifluoromethyl Vinyl Sulfide: A Building Block for the Synthesis of CF₃S-Containing Isoxazolidines

Author(s) -

Alejandra RiescoDomínguez,

Jeroen van de Wiel,

Trevor A. Hamlin,

Bas van Beek,

Stephen D. Lindell,

Daniel BlancoAnia,

F. Matthias Bickelhaupt,

Floris P. J. T. Rutjes

Publication year - 2018

Publication title -

the journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.2

H-Index - 228

eISSN - 1520-6904

pISSN - 0022-3263

DOI - 10.1021/acs.joc.7b02639

Subject(s) - trifluoromethyl , sulfide , chemistry , cycloaddition , sulfanyl , block (permutation group theory) , organic chemistry , medicinal chemistry , polymer chemistry , catalysis , mathematics , alkyl , geometry

Trifluoromethyl vinyl sulfide, a potential building block for pharmaceutically and agrochemically relevant products, is prepared and used for the first time in high-pressure-mediated 1,3-dipolar cycloaddition reactions with nitrones to synthesize (trifluoromethyl)sulfanyl isoxazolidines.

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