The Synthesis of Certain Phomentrioloxin A Analogues and Their Evaluation as Herbicidal Agents | Zendy

Ehab S. Taher | Zendy; Prue Guest | Zendy; Amanda Benton | Zendy; Xinghua Ma | Zendy; Martin G. Banwell | Zendy; Anthony C. Willis | Zendy; Tobias Seiser | Zendy; Trevor Newton | Zendy; Johannes Hutzler | Zendy

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The Synthesis of Certain Phomentrioloxin A Analogues and Their Evaluation as Herbicidal Agents

Author(s) -

Ehab S. Taher,

Prue Guest,

Amanda Benton,

Xinghua Ma,

Martin G. Banwell,

Anthony C. Willis,

Tobias Seiser,

Trevor Newton,

Johannes Hutzler

Publication year - 2016

Publication title -

the journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.2

H-Index - 228

eISSN - 1520-6904

pISSN - 0022-3263

DOI - 10.1021/acs.joc.6b02372

Subject(s) - chemistry , combinatorial chemistry , organic chemistry , stereochemistry

A series of 28 analogues of the phytotoxic geranylcyclohexentriol (-)-phomentrioloxin A (1) has been synthesized through cross-couplings of various enantiomerically pure haloconduritols or certain deoxygenated derivatives with either terminal alkynes or borylated alkenes. Some of these analogues display modest herbicidal activities, and physiological profiling studies suggest that analogue 4 inhibits photosystem II in isolated thylakoids in vitro.

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