Broad Scope Aminocyclization of Enynes with Cationic JohnPhos–Gold(I) Complex as the Catalyst | Zendy

Ricarda Miller | Zendy; Javier Carreras | Zendy; Michael E. Muratore | Zendy; Morgane Gaydou | Zendy; Francesco Camponovo | Zendy; Antonio M. Echavarren | Zendy

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Broad Scope Aminocyclization of Enynes with Cationic JohnPhos–Gold(I) Complex as the Catalyst

Author(s) -

Ricarda Miller,

Javier Carreras,

Michael E. Muratore,

Morgane Gaydou,

Francesco Camponovo,

Antonio M. Echavarren

Publication year - 2016

Publication title -

the journal of organic chemistry

Language(s) - English

Resource type - Journals

eISSN - 1520-6904

pISSN - 0022-3263

DOI - 10.1021/acs.joc.5b02607

Subject(s) - chemistry , cationic polymerization , catalysis , adduct , palladium , organic chemistry , alkyl , scope (computer science) , combinatorial chemistry , computer science , programming language

A practical aminocyclization of 1,6-enynes with a wide variety of substituted anilines, including N-alkyl anilines, has been achived by using cationic [JohnPhosAu(MeCN)]SbF6 as a general purpose catalyst. The resulting adducts can be easily converted into polycyclic compounds by palladium- and gold-catalyzed reactions.

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