Acyloxylation of 1,4-Dioxanes and 1,4-Dithianes Catalyzed by a Copper–Iron Mixed Oxide | Zendy

Ana Leticia GarcíaCabeza | Zendy; Rubén MarínBarrios | Zendy; F. Javier MorenoDorado | Zendy; Marı́a J. Ortega | Zendy; Hilario Vidal | Zendy; José M. Gatica | Zendy; Guillermo M. Massanet | Zendy; Francisco M. Guerra | Zendy

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Acyloxylation of 1,4-Dioxanes and 1,4-Dithianes Catalyzed by a Copper–Iron Mixed Oxide

Author(s) -

Ana Leticia GarcíaCabeza,

Rubén MarínBarrios,

F. Javier MorenoDorado,

Marı́a J. Ortega,

Hilario Vidal,

José M. Gatica,

Guillermo M. Massanet,

Francisco M. Guerra

Publication year - 2015

Publication title -

the journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.2

H-Index - 228

eISSN - 1520-6904

pISSN - 0022-3263

DOI - 10.1021/acs.joc.5b01043

Subject(s) - heteroatom , catalysis , copper , chemistry , oxide , copper oxide , combinatorial chemistry , organic chemistry , inorganic chemistry , polymer chemistry , ring (chemistry)

The use of a copper-iron mixed oxide as a heterogeneous catalyst for the efficient synthesis of α-acyloxy-1,4-dioxanes and 1,4-dithianes employing t-butyl peroxyesters is reported. The preparation and characterization of the catalyst are described. The effect of the heteroatoms and a plausible mechanism are discussed. The method is operationally simple and involves low-cost starting materials affording products in good to excellent yields.

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