Open AccessDirect Allylation of Quinones with Allylboronates
Author(s) -
HongPing Deng,
Dong Wang,
Kálmán J. Szabó
Publication year - 2015
Publication title -
the journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.2
H-Index - 228
eISSN - 1520-6904
pISSN - 0022-3263
DOI - 10.1021/acs.joc.5b00264
Subject(s) - chemistry , benzoquinone , naphthoquinone , stereochemistry , organic chemistry
Allylboronates undergo C-H allylation of unsubstituted or monosubstituted benzoquinone and naphthoquinone substrates. In the case of 2,5- or 2,6-disubstituted quinones addition involving the substituted carbon takes place. Allylation with stereodefined allylboronates occurs with retention of the configuration.
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