Dyedauxiliary Groups, an Emerging Approach in Organic Chemistry. The Case of Arylazo Sulfones | Zendy

Di Qiu | Zendy; Chang Lian | Zendy; Jinshan Mao | Zendy; Maurizio Fagi | Zendy; Stefano Protti | Zendy

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Dyedauxiliary Groups, an Emerging Approach in Organic Chemistry. The Case of Arylazo Sulfones

Author(s) -

Di Qiu,

Chang Lian,

Jinshan Mao,

Maurizio Fagi,

Stefano Protti

Publication year - 2020

Publication title -

the journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.2

H-Index - 228

eISSN - 1520-6904

pISSN - 0022-3263

DOI - 10.1021/acs.joc.0c01895

Subject(s) - moiety , radical , aryl , chemistry , substrate (aquarium) , combinatorial chemistry , organic synthesis , photocatalysis , group (periodic table) , carbon fibers , range (aeronautics) , photochemistry , organic chemistry , catalysis , computer science , materials science , alkyl , oceanography , geology , algorithm , composite number , composite material

The number of research papers that report photocatalyst-free protocols is currently increasing. Among the different approaches proposed, the conversion of a strong C-X bond of a stable substrate into a photolabile reactive moiety has been recently proposed. In this Synopsis, we introduce the so-dubbed dyedauxiliary group strategy by focusing on arylazo sulfones that are bench stable and visible-light responsive derivatives of anilines that have been exploited as precursors of a wide range of intermediates, including carbon-centered radicals as well as aryl cations.

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