Density and Viscosity of Partially Carbonated Aqueous Solutions Containing a Tertiary Alkanolamine and Piperazine at Temperatures between 298.15 and 353.15 K
Author(s) -
Clemens F. Patzschke,
Jiafei Zhang,
Paul S. Fennell,
J. P. Martin Trusler
Publication year - 2017
Publication title -
journal of chemical and engineering data
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.719
H-Index - 132
eISSN - 1520-5134
pISSN - 0021-9568
DOI - 10.1021/acs.jced.7b00144
Subject(s) - piperazine , alkanolamine , viscosity , aqueous solution , chemistry , amine gas treating , mass fraction , tertiary amine , thermodynamics , analytical chemistry (journal) , organic chemistry , physics
Measurements for the density and viscosity of partially carbonated solutions containing water, piperazine (PZ), and a tertiary amine, which was either dimethylaminoethanol (DMAE) or 2-diethylaminoethanol (DEAE), were conducted with total amine mass fractions of 30% and 40% over a temperature range from 298.15 to 353.15 K. Density and viscosity correlations of these mixtures were developed as functions of amine mass fraction, CO2 loading, and temperature. For both systems investigated, the average absolute relative deviations of the experimental data from these correlation are approximately 0.2% for density and 3% for viscosity. The correlations will be useful for thermodynamic analysis and computer simulations of carbon capture processes utilizing these promising blended amine systems
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