Decanuclear Cluster-Based Metal–Organic Framework with a (3,11)-Connected Topology and Highly Sensitive 2,4,6-Trinitrophenol Detection | Zendy

Jinfang Zhang | Zendy; Yuhang Liu | Zendy; Jiaoyang Feng | Zendy; Linpei Gong | Zendy; Mark G. Humphrey | Zendy; Chi Zhang | Zendy

Open Access

Decanuclear Cluster-Based Metal–Organic Framework with a (3,11)-Connected Topology and Highly Sensitive 2,4,6-Trinitrophenol Detection

Author(s) -

Jinfang Zhang,

Yuhang Liu,

Jiaoyang Feng,

Linpei Gong,

Mark G. Humphrey,

Chi Zhang

Publication year - 2019

Publication title -

inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.348

H-Index - 233

eISSN - 1520-510X

pISSN - 0020-1669

DOI - 10.1021/acs.inorgchem.9b00745

Subject(s) - chemistry , cluster (spacecraft) , luminescence , aqueous solution , metal , aqueous medium , topology (electrical circuits) , nanotechnology , crystallography , combinatorial chemistry , organic chemistry , optoelectronics , physics , materials science , mathematics , combinatorics , computer science , programming language

A 3D heterothiometallic cluster-based metal-organic framework was constructed from the new oligomeric decanuclear heterothiometallic building clusters [W 2 (μ 3 -S) 6 (μ 4 -S) 2 Cu 8 ] 4+ , tetradentate 3-abpt units (3-abpt = 4-amino-3,5-bis(3-pyridyl)-1,2,4-triazole), and CN - bridges. It possesses an unprecedented (3,11)-connected architecture, luminescence, and highly sensitive 2,4,6-trinitrophenol (TNP) sensing properties in both organic and aqueous media.

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