Lanthanide-Based Coordination Polymers With 1,4-Carboxyphenylboronic Ligand: Multiemissive Compounds for Multisensitive Luminescent Thermometric Probes | Zendy

Ahmad Abdallah | Zendy; Stéphane Freslon | Zendy; Fan Xiao | Zendy; Amandine Rojo | Zendy; Carole Daiguebonne | Zendy; Yan Suffren | Zendy; Kévin Bernot | Zendy; Guillaume Calvez | Zendy; Thierry Roisnel | Zendy; Olivier Guillou | Zendy

Open Access

Lanthanide-Based Coordination Polymers With 1,4-Carboxyphenylboronic Ligand: Multiemissive Compounds for Multisensitive Luminescent Thermometric Probes

Author(s) -

Ahmad Abdallah,

Stéphane Freslon,

Fan Xiao,

Amandine Rojo,

Carole Daiguebonne,

Yan Suffren,

Kévin Bernot,

Guillaume Calvez,

Thierry Roisnel,

Olivier Guillou

Publication year - 2018

Publication title -

inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.348

H-Index - 233

eISSN - 1520-510X

pISSN - 0020-1669

DOI - 10.1021/acs.inorgchem.8b02681

Subject(s) - chemistry , lanthanide , luminescence , ligand (biochemistry) , polymer , combinatorial chemistry , organic chemistry , optoelectronics , ion , receptor , biochemistry , physics

Reactions in water of lanthanide chlorides with the sodium salt of 1,4-carboxyphenylboronic acid lead to two series of isostructural compounds with respective general chemical formulas [Ln(cpb) 3 (H 2 O) 2 ] ∞ for Ln = La or Ce and [Ln(cpbOH)(H 2 O) 2 ·(cpb)] ∞ for Ln = Pr-Lu (except Pm) plus Y. Heterolanthanide coordination polymers that are isostructural to the second series have been synthesized, and their photophysical properties have been studied. This study evidences that it is possible to design multiemissive lanthanide-based coordination polymers that could find their application as multigauge luminescent thermometric probes.

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