Open AccessRedox-Active Metallacarborane-Decorated Octasilsesquioxanes. Electrochemical and Thermal Properties
Author(s) -
Justo CabreraGonzález,
Víctor Sánchez Arderiu,
Clara Viñas,
Teodor Parella,
Francesç Teixidor,
Rosario Núñez
Publication year - 2016
Publication title -
inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.348
H-Index - 233
eISSN - 1520-510X
pISSN - 0020-1669
DOI - 10.1021/acs.inorgchem.6b02394
Subject(s) - chemistry , redox , electrochemistry , thermal stability , solubility , polymer chemistry , chemical engineering , inorganic chemistry , organic chemistry , electrode , engineering
Polyanionic and electroactive hybrids based on octasilsesquioxanes bearing metallacarborane units are developed. They show remarkable solubility in organic solvents and outstanding thermal stability. The metallacarboranes act as independent units simultaneously undergoing the reversible redox process.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom