Furnishing Amine-Functionalized Metal–Organic Frameworks with the β-Amidoketone Group by Postsynthetic Modification | Zendy

William J. Gee | Zendy; Laura K. Cadman | Zendy; Harina Amer Hamzah | Zendy; Mary F. Mahon | Zendy; Paul R. Raithby | Zendy; Andrew D. Burrows | Zendy

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Furnishing Amine-Functionalized Metal–Organic Frameworks with the β-Amidoketone Group by Postsynthetic Modification

Author(s) -

William J. Gee,

Laura K. Cadman,

Harina Amer Hamzah,

Mary F. Mahon,

Paul R. Raithby,

Andrew D. Burrows

Publication year - 2016

Publication title -

inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.348

H-Index - 233

eISSN - 1520-510X

pISSN - 0020-1669

DOI - 10.1021/acs.inorgchem.6b01917

Subject(s) - chemistry , diketene , amine gas treating , metal organic framework , crystallinity , solid state , group (periodic table) , scope (computer science) , polymer chemistry , combinatorial chemistry , organic chemistry , crystallography , adsorption , computer science , programming language

Postsynthetic modification (PSM) of amino-functionalized metal-organic frameworks (MOFs) to those bearing pendant β-amidoketone arms using diketene is herein reported. Three unique MOF families demonstrate the scope of this transformation, which both is atom-economical and yields high conversions. In each case, the crystallinity was retained, and instances of exceptional solid-state ordering were observed in the PSM products, which has allowed detailed crystallographic characterization in multiple instances.

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